Ni-Si coatings consisting of mainly NiSi2 and NiSi were deposited on a carbon steel by air plasma spraying. Isothermal oxidation tests of the carbon steel substrates with the Ni-Si coatings at 500-800 ℃ have been carried out. The result indicated that a protective SiO2-based oxide scale was formed on the surface of the coatings after oxidation. On the other hand, during oxidation, phase transformation occurred among the NiSi2, NiSi and Ni2Si phases constructing the Ni-Si coatings. This was caused by the extraction of silicon from the silicides and the reformation of silicides at the silcide/Si-blocks interface. Above 700 ℃, the outward diffusion of iron and carbon became very fast and consequently decarburization happened at the coating/substrates interface, which induced the formation of pores in the substrates near the interface. In addition, grain boundary oxidation of Cr in the steel substrate was observed above 700 ℃.
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